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KMID : 1059520130570020272
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Journal of the Korean Chemical Society
2013 Volume.57 No. 2 p.272 ~ p.278
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Ginger Extract as Green Corrosion Inhibitor for Steel in Sulfide Polluted Salt Water
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Fouda Abd El-Aziz S.
Nazeer Ahmed Abdel
Ibrahim Mohamed
Fakih Mohamed
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Abstract
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Extract of ginger has been evaluated as a green inhibitor for the corrosion of steel in sulfide polluted NaCl solution using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Potentiodynamic polarization measurements showed that this extract acts as a mixed type inhibitor but mainly inhibits the cathodic reaction. The inhibition efficiency was found to increase with inhibitor concentration reaching to approximately 83.9% using 250 ppm of ginger. Nyquist plots show a single capacitive loop in uninhibited and inhibited solutions. From EFM the causality factors are very close to theoretical values which indicate that the measured data are of good quality. The adsorption process of the studied extract on steel surface obeys Temkin adsorption isotherm. The results obtained from the different electrochemical techniques were in good agreement which prove the validity of these tools in measurement of corrosion rate. Ginger extract has no effect on Escherichia Coli and can be applied safely on waste water treatment plants.
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KEYWORD
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Corrosion inhibition, Steel, NaCl, Na2S, Green inhibitor (ginger)
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